Ac white led device

ABSTRACT

An Alternate Current (AC) white Light-Emitting Diode (LED) device is provided, which belongs to the technical field of white LED manufacturing. The problem to be solved by the present invention is to low-costly overcome a series of deficiencies such as the stroboflash of an AC driven LED, and the heat dissipation difficulty caused by an integrated packaging of multiple LEDs. A white LED unit includes an LED chip and a light emitting material that can emit light when being excited by the LED chip. The luminous lifetime of the light emitting material is 1˜100 ms. The LED chip only comprises one PN junction. The light emitted by the LED chip is mixed with the light emitted by the light emitting material to form white light. The white LED unit is driven by AC with a frequency not more than 100 Hz. The white LED device of prevent invention uses the single PN junction chip, rather than the prior integrated packaged AC multi-LED chip.

FIELD OF THE INVENTION

The present invention relates to an Alternate Current (AC) whiteLight-Emitting Diode (LED) device, which belongs to the technical fieldof white LED manufacturing, and particularly, to an AC white LED devicemade of a light emitting material having a specific lifetime.

BACKGROUND OF THE INVENTION

Currently, the LED is used in the fields of illumination, display,backlight, etc., and attracts extensive attentions due to its advantagessuch as energy saving, durable and pollution free. There are manysolutions for implementing the white LED, and presently the most maturetechnical solution for manufacturing the white LED is to implement whitelight emission by combining the blue light LED chip with the yellowfluorescent powder. Appl. Phys. Lett. published in 1967 (refer to volume11, page 53) reports a light emitting material Y₃Al₅O₁₂:Ce³⁺ which emitsyellow light, with a maximum light emitting wavelength of 550 nm and alifetime less than 100 ns. Appl. Phys. A published in 1997 (refer tovolume 64, page 417) reports that white light emission of an LED isimplemented using the yellow light emitted by Y₃Al₅O₁₂:Ce³⁺ and bluelight gallium nitride, which is the most mature technical solution formanufacturing the white LED at present. But in practical applications,with the increase of the temperature of the working device, the luminousintensities of the blue light LED chip and the fluorescent powderdecrease, wherein the luminous intensity of the fluorescent powderdecreases obviously, thus the usage of the LED is influenced.

The conventional LED is driven by the direct current (DC), but most ofthe household, industrial, commercial or public electricity is suppliedin the form of AC, thus a rectifier transformer must be accompanied forAC-DC conversion when the LED is used for illumination, etc. But in theprocess of AC-DC conversion, a power loss up to 15˜30% will be caused.In addition, the conversion device has a short lifetime and a high cost,while it requires a lot of works and time in installation, so theefficiency is low.

The American U.S. Pat. No. 7,489,086 B2 “AC LIGHT EMITTING DIODE AND ACLED DRIVE METHODS AND APPARATUS” provides an AC LED device, which mainlyenables an integrated packaged LED device to work in a frequency higherthan 100 Hz, so as to compensate for the stroboflash of light emissionof the LED device in the AC working state with a visual persistenceeffect of naked eyes. The Chinese patent No. 200910307357.3 discloses alight emitting material Y₂O₃.Al₂O₃.SiO₂:Ce.B.Na.P with yellow longafterglow phenomenon and a white LED device using the same.

The Chinese patent CN100464111C discloses an AC LED lamp using LED chipsof different emitting colors connected in parallel in an AC powersupply, and it mainly describes different colors of LED chips usedtogether for emitting white light, and the specific circuit thereof,such as red, green and blue light emitting chips. The internationalpatent WO2004/023568A1 “LIGHT-EMITTING DEVICE HAVING LIGHT-EMITTINGELEMENTS” proposes to install a plurality of small LED chip arrays on asapphire substrate, so as to provide a light emitting device that can bedriven by an AC power supply. On the basis of similar ideas, the SeoulSemiconductor of South Korea and the Industrial Technology ResearchInstitute of Taiwan integratedly package a lot of superfine LED grainsonto a substrate referred to as AC LED chip. The core of the above ACLED technology is the microelectronic circuit processing technologyintegratedly packaging a lot of micro grains, e.g., the AC LED chipmanufactured by the Industrial Technology Research Institute of Taiwanintegratedly packages hundreds of tiny LEDs in an area of 1 mm². But itis difficult to process the AC LED chip, and problems such as poor heatdissipation will be caused as the large number of microchips areintegrated in a narrow substrate space.

In order to enable the white LED device to overcome the stroboflashunder the AC power supply mode and improve the heat dissipation, personsskilled in the art always make unremitting efforts.

SUMMARY OF THE INVENTION

The technical problem to be solved by the present invention is toprovide a new white LED device, so as to overcome a series ofdeficiencies such as the stroboflash under the AC power supply mode andthe heat dissipation difficulty of the existing white LED device.

The technical solutions of the present invention: a white Light-EmittingDiode (LED) unit, comprising an LED chip and a light emitting materialcapable of emitting light when being excited by the LED chip,characterized in that, the LED chip only comprises one light emitting PNjunction, the luminous lifetime of the light emitting material is 1 to100 ms, the luminous brightness of powered off chip under non-constantcurrent condition is compensated for with afterglow of the lightemitting material, and the light emitted by the LED chip is mixed withthe light emitted by the light emitting material to form white light.

Further, a white LED unit, comprising an LED chip and a light emittingmaterial capable of emitting light when being excited by the LED chip,wherein the LED chip only comprises one light emitting PN junction, theluminous lifetime of the light emitting material is 10-30 ms, and thelight emitted by the LED chip is mixed with the light emitted by thelight emitting material to form white light.

According to the definition of luminescence, the luminous lifetime ofthe light emitting material is the time for decreasing the luminousintensity of the material to be 1/e of the maximum intensity in theexcitation.

The white LED unit is driven by Alternate Current (AC) with a frequencynot more than 100 Hz, and preferably 50 to 60 Hz. The luminousbrightness of the powered off chip under non-constant current conditionmay be compensated for with afterglow of the light emitting material, sothat the AC driving is more practical.

The white LED unit of prevent invention overcomes the stroboflash causedby the AC power supply by using the normal single PN junction LED chip,rather than the prior AC LED chip integrating a plurality of micrograins, thus the production is simple and the cost is low.

In which, the light emitted by the LED chip is ultraviolet light in arange of 200 nm to 380 nm or visible light in a range of 380 nm to 780nm.

In the present invention, the light emitting material emits light whenbeing excited by the LED chip, and the overall visual effect of theemitted light is the white light, or the overall visual effect of thelight emitted by the light emitting material and the light emitted bythe chip is the white light.

The light emitting material is at east one of CaS:Eu²⁺; CaS:Bi²⁺, Tm³⁺;ZnS:Tb³⁺; CaSrS₂:Eu²⁺, Dy³⁺; SrGa₂S₄:Dy³⁺; Ga₂O₃:Eu³⁺;(Y,Gd)BO₃:Eu³⁺:Zn₂SiO₄:Mn²⁺; YBO₃:Tb³⁺; Y(V,P)O₄:Eu³⁺; SrAl₂O₄:Eu²⁺;SrAl₂O₄:Eu²⁺, B³⁺; SrAl₂O₄:Eu²′, Dy³⁺, B³⁺; Sr₄Al₁₄O₂₅:Eu²⁺;Sr₄Al₁₄O₂₅:Eu²⁺, Dy³⁺, B³⁺; BaAl₂O₄:Eu²⁺; CaAl₂O₄:Eu²⁺; Sr₃SiO₅:Eu²⁺,Dy³⁺; BaMgAl₁₀O₁₇:Eu²⁺, Mn²; Tb(acac)₂(AA)phen; Y₂O₂S:Eu³⁺; Y₂SiO₅:Tb³⁺;SrGa₂S₄:Ce³⁺; Y₃(Al,Ga)₅O₁₂:Tb³⁺; Ca₂Zn₄Ti₁₅O₃₆:Pr³⁺; CaTiO₃:Pr³⁺;Zn₂P₂O₇:Tm³⁺; Ca₂P₂O₇:Eu²⁺, Y³⁺; Sr₂P₂O₇:Eu²⁺, Y³⁺; Lu₂O₃:Tb³⁺;Sr₂Al₆O₁₁:Eu²⁺; Mg₂SnO₄:Mn²⁺; CaAl₂O₄:Ce³⁺, Tb³⁺; Sr₄Al₁₄O₂₅:Tb³⁺;Ca₁₀(PO₄)₆(F,Cl)₂:Sb³⁺, Mn²; Sr₂MgSi₂O₇:Eu²⁺; Sr₂CaSi₂O₇:Eu²⁺;Zn₃(PO4)₂:Mn²⁺, Ga³⁺; CaO:Eu³⁺:Y₂O₂S:Mg²⁺, Ti³⁺:Y₂O₂S:Sm³⁺;SrMg₂(PO₄)₂:Eu²⁺, Gd³⁺; BaMg₂(PO₄)₂:Eu²⁺, Gd³⁺; Zn₂SiO₄:Mn²⁺, As⁵⁺;CdSiO₃:Dy³⁺; MgSiO₃:Eu²⁺ and Mn²⁺.

The preferable light emitting material is at least one of Ca₂P₂O₇:Eu²⁺,Y³⁺; Sr₂P₂O₇:Eu²⁺, Y³⁺; Sr₄Al₁₄O₂₅:Eu²⁺, Dy³⁺, B³⁺; SrAl₂O₄:Eu²⁺, Dy³⁺,B³⁺; Zn₂SiO₄:Mn²⁺, As⁵⁺; Zn₂P₂O₇:Tm³⁺; Y₂O₂S:Eu³⁺; Sr₄Al₁₄O₂₅:Tb³⁺;Zn₃(PO₄)₂:Mn²⁺, Ga³⁺; and CaS:Eu²⁺.

In the white LED unit of the present invention, each LED chip onlycomprises one light emitting PN junction.

The white LED device of the present invention comprises the white LEDunit and a drive circuit. The AC driven drive circuit is aunidirectional series circuit, a reverse parallel circuit or a bridgerectifier circuit, as illustrated in FIGS. 1 to 4, or arbitrarycombinations thereof. The frequency of the AC driven drive circuit isnot more than 100 Hz.

In addition, the white LED device of the present invention furthercomprises a light guide covering layer, which is a non-planar lightguide structure. Through the light guide covering layer, the lightemitted by the LED chip and the light emitted by the light emittingmaterial is reflected, refracted, diffused, dodged and finally mixed tooutput uniform light.

In which, the light guide covering layer is a lens or other transparentcovering layer, which can be doped with particles of non-light-emittingmaterial with a diameter less than 5 μm, so that the light from the chipis diffused more uniformly.

The present invention has the following beneficial effects:

The prior white LED device uses YAG:Ce as the light emitting material,which will cause stroboflash phenomenon due to the change of AC cycle ata power frequency below 100 Hz. The present invention can maintain thelight emission when the excitation light source disappears since thelight emitting material having a specific lifetime is used, thus in anAC white LED device based on the solution of the present invention, whenthe current cycle changes, the light emission of the light emittingmaterial can be maintained for a certain time in the cycle, therebycompensating for the stroboflash of the LED chip caused by the ACfluctuation, and keeping a stable light output from the white LED devicein the AC cycle. In addition, as the LED chip does not work in a half ofthe AC cycle, the heat effect is decreased, which is beneficial toovercome series of difficulties caused by the chip heating in the priorwhite LED device.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates a schematic diagram of a unidirectional seriescircuit of an AC white LED device of the present invention;

FIG. 2 illustrates a schematic diagram of a reverse parallel circuit ofan AC white LED device of the present invention;

FIG. 3 illustrates a schematic diagram of a bridge rectifier circuithaving a normal conducted LED chip of an AC white LED device of thepresent invention;

FIG. 4 illustrates a schematic diagram of a bridge rectifier circuithaving no normal conducted LED chip of an AC white LED device of thepresent invention;

FIG. 5 illustrates a schematic diagram of the constitution of a whiteLED unit, wherein 1 represents a light emitting material or a lightemitting layer made of the light emitting material and a transparentmedium, and 2 represents an LED chip; and

FIG. 6 illustrates color points of Examples 1 to 8 in CIE1931 chromaticdiagram, wherein digits 1 to 8 are corresponding to Examples 1 to 8,respectively.

The above contents of the present invention are further described indetails through the following embodiments. But it shall not beappreciated that the range of the subject matter of the presentinvention is limited thereto. Any technology implemented based on theabove contents of the present invention shall fall within the range ofthe present invention. Particularly, about the constitution of the basiccircuit, the embodiments of the present invention only give the simplestreverse parallel circuit, but the AC white LED device of the presentinvention is not limited thereto, and it further includes for example aunidirectional series circuit and a bridge rectifier circuit.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Examples 1 to 8 overcome the stroboflash by implementing the white LEDdevice made of a light emitting material shown in Table 1 and merchantnormal LED chip in a general packaging technology, without usingintegrated chip dedicated to the AC LED.

Examples 1 to 8

TABLE 1 LED chip (light emitting Lifetime of light emitting Examplewavelength) Light emitting material material (ms) 1 Ultraviolet (254 nm)45 wt % Zn₂P₂O₇: Tm³⁺ 10 55 wt % Zn₃(PO4)₂: Mn²⁺, Ga³⁺ 2 Ultraviolet(254 nm) CaAl₂O₄: Dy³⁺ 25 3 Ultraviolet (310 nm) 15 wt % Sr₂P₂O₇: Eu²⁺,Y³⁺ 30 30 wt % Sr₄Al₁₄O₂₅: Eu²⁺, Dy³⁺, B³⁺ 15 wt % Ca₄O(PO₄)₂: Eu²⁺, 40wt % Zn₃(PO₄)₂: Mn²⁺, Ga³⁺ 4 Ultraviolet (365nm) 10 wt % Sr₂P₂O₇: Eu²⁺,Y³⁺ 14 30 wt % Sr₄Al₁₄O₂₅: Eu²⁺ 60 wt % Y₂O₂S: Eu³⁺ 5 Purple light (400nm) 50 wt % SrMg₂(PO₄)₂: Eu²⁺, Gd³⁺ 4 50 wt % Ca₄O(PO₄)₂: Eu²⁺ 6 Purplelight (400 nm) 40 wt % Sr₄Al₁₄O₂₅: Eu²⁺ 1 60 wt % Y₂O₂S: Eu³⁺ 7 Bluelight (450 nm) 30 wt % SrAl₂O₄: Eu²⁺, B³⁺ 100 70 wt % CaS: Eu²⁺ 8 Bluelight (460 nm) 60 wt % Y₂O₂S: Mg²⁺, Ti³⁺ 48 40 wt % SrAl₂O₄: Eu²⁺

Test Example 1 Luminescence Properties of the AC White LED Device of thePresent Invention

Table 2 shows the luminous brightness of the photos shot within 20 ms bythe AC white LED device driven under 50 Hz AC using a high-speedscientific camera Sarnoff CAM512 which takes 300 photos per second.Reference 1 is an AC driven white LED device made in the same manner asexamples 1 to 8 using the merchant 460 nm blue light chip packaged witha yellow light emitting material YAG:Ce (the luminous lifetime is 100ns). Reference 2 is an AC driven white LED device made in the samemanner as examples 1 to 8 using the merchant 460 nm blue light chippackaged with long lifetime materials SrA1204: Eu, Dy and Y2O2S: Eu, Mg,Ti (the luminous lifetime is more than 1s). In table 2, the brightnessdata is relative brightness without dimension.

TABLE 2 Time 3.33 6.66 9.99 13.32 16.65 19.98 ms ms ms ms ms msBrightness of reference 1 2265 3466 0 2153 3570 0 Brightness ofreference 2 746 998 670 702 965 712 Brightness of example 1 2931 30251455 3187 3443 1665 Brightness of example 2 3140 3373 1654 2884 34371877 Brightness of example 3 3200 3423 1506 3135 3362 1656 Brightness ofexample 4 2910 3190 1652 2723 3245 1850 Brightness of example 5 22502734 1468 2114 2800 1420 Brightness of example 6 2109 2636 1150 22132858 1163 Brightness of example 7 2017 2420 1569 2115 2654 1510Brightness of example 8 1879 2000 1270 1746 2123 1303

Table 3 gives the normalized value of be maximum luminous brightness ofeach sample in the examples of Table 2,

TABLE 3 Normalized Time brightness 3.33 6.66 9.99 13.32 16.65 19.98ratio ms ms ms ms ms ms Reference 1 0.63445 0.97087 0 0.60308 1 0Reference 2 0.74749 1 0.67134 0.70341 0.96693 0.71343 Example 1 0.851290.87859 0.4226 0.92565 1 0.48359 Example 2 0.91359 0.98138 0.481230.8391 1 0.54612 Example 3 0.93485 1 0.43996 0.91586 0.9821 0.48379Example 4 0.89676 0.98305 0.50909 0.83914 1 0.57011 Example 5 0.803570.97643 0.52429 0.755 1 0.50714 Example 6 0.73793 0.92232 0.402380.77432 1 0.40693 Example 7 0.75998 0.91183 0.59118 0.79691 1 0.56895Example 8 0.88507 0.94206 0.59821 0.82242 1 0.61375

As can be seen from Tables 2 and 3, the luminescence of the presentinvention is stable and slightly fluctuant in the AC cycle. But aboutreference 1, i.e., a white LED device made of the merchant blue lightchip packaged with the conventional yellow light emitting materialYAG:Ce having a short luminous lifetime, the luminescence is unstableand largely fluctuant in the AC cycle. It is clear that the presentinvention effectively and low-costly overcomes the stroboflash of the ACLED.

Although as illustrated by reference 2, the luminescence of the whiteLED device made of the light emitting material with long luminouslifetime is also slightly fluctuant in the AC cycle, the energy obtainedby the material when the exciting light exists cannot be releasedquickly, so the light is weak (refer to Table 1), which isdisadvantageous to be used as a light emitting material.

Table 4 shows the color coordinates and the color temperatures of theexamples in Table 1 (measured using Minolta colorimeter CS-100A).

TABLE 4 CIE Color Coordinates and Color Temperatures Color Related colorCoordinates CIEx CIEy temperature Example 1 0.4076 0.3807 3312K Example2 0.3410 0.3102 4997K Example 3 0.3279 0.2939 5725K Example 4 0.33200.3210 5496K Example 5 0.3802 0.3566 3815K Example 6 0.3503 0.3002 4441KExample 7 0.3104 0.3154 6746K Example 8 0.3484 0.3516 4867K

As can be seen from Table 4, the above examples enable the white LEDdevice to emit white light. The color point positions in the lightemissions of respective examples in the CIE1931 chromaticity diagram areshown in FIG. 6.

Test Example 2 Light Attenuation of the AC White LED Device of thePresent Invention

Table 5 shows the light attenuation data of examples 1 to 18 and thereference. The reference is a white LED device obtained by installing awhite LED chip made of the merchant 460 nm blue light chip packaged withYAG:Ce in the general DC power supply 1.0 mode at present. The testmethod is as follows: electrifying the AC white LED device of theexample and the reference device, and measuring their luminousbrightness in a certain interval with Minolta colorimeter CS-100. Theresults are shown in FIG. 5. The data in FIG. 5 is relative brightnesswithout dimension, and the initial data is normalized.

TABLE 5 Time 1 h 1,000 h 1,500 h 2,500 h Brightness of 100 98 97.1 96.3reference Brightness of 100 99.8 99.5 99.1 example 1 Brightness of 10099.5 99.4 99.3 example 2 Brightness of 100 99.6 99.5 99 example 3Brightness of 100 99.7 99.3 99 example 4 Brightness of 100 99.8 99.498.6 example 5 Brightness of 100 99.5 99 98 example 6 Brightness of 10099.4 99 98.3 example 7 Brightness of 100 99.3 99 98 example 8

As can be seen from the data in FIG. 5, the AC white LED device of thepresent invention has a light attenuation less than the AC while LEDdevice in the prior ad.

1-10. (canceled)
 11. A white Light-Emitting Diode (LED) device, the LEDdevice comprising: a circuit comprising two or more diode, wherein eachdiode in the circuit is a white LED comprising a LED chip and a lightemitting material capable of emitting light when excited by the LEDchip, wherein the LED chip is driven directly by Alternating Current(AC) with a frequency of not more than 100 Hz, and wherein a luminouslifetime of the light emitting material is 1 to 100 ms.
 12. The whiteLED device of claim 11, wherein the light emitting material is one or acombination of CaS:Eu²⁺, SrAl₂O₄:Eu²⁺, SrAl₂O₄:Eu²⁺, Sr₄Al₁₄O₂₅:Eu²⁺,Sr₄Al₁₄O₂₅:Eu²⁺, Y₂O₂S:Eu³⁺, Zn₂P₂O₇:Tm³⁺, Sr₂P₂O₇:Eu²⁺, Zn₃(PO₄)₂:Mn²⁺,Y₂O₂S:Mg²⁺, SrMg₂(PO₄)₂:Eu²⁺, CaAl₂O₄:Dy³⁺, Ca₄O(PO₄)₂:Eu²⁺, B³⁺, Ga³⁺,Gd³⁺, Y³⁺, Dy³⁺ and Ti³⁺.
 13. The white LED device of claim 11, whereinthe circuit is a unidirectional series circuit.
 14. The white LED deviceof claim 11, wherein the circuit is a reverse parallel circuit.
 15. Thewhite LED device of claim 11, wherein the circuit is a bridge rectifiercircuit.
 16. The white LED device according to claim 11, wherein the LEDchip is driven by Alternating Current (AC) with a frequency of 50 to 60Hz.
 17. The white LED device according to claim 11, wherein the luminouslifetime of the light emitting material is 10 to 30 ms.
 18. The whiteLED device according to claim 11, wherein the light emitted by the LEDchip is ultraviolet light in a range of 200 nm to 380 nm or visiblelight in a range of 380 nm to 780 nm.
 19. The white LED device accordingto claim 11, further comprising a light guide covering layer.
 20. Thewhite LED device according to claim 19, wherein the light guide coveringlayer is doped with particles of non-light-emitting material with adiameter less than 5 μm.
 21. The white LED device according to claim 11,wherein the LED chip comprises a single light emitting PN junction.